It was never a command. It was always and it is still now a setting. Just read what podbot.cfg says about that.
Quote:
Originally Posted by podbot.cfg
# Changing the setting below forces bots joining to certain team.
# Useful if You want to have always bots in one team against humans.
# Argument values: "ANY", "T", "CT". Default is "ANY".
pb_bot_join_team "ANY"
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Settings are with underscore line after pb - commands - without it.
Next time read
stickies first - then You know where is the place to ask questions.

I'm moving Your topic to the right place.