How did You install podbot mm? Did You use the fullpack with all needed configs,chats and waypoints or You just downloaded some binaries?
Try to disable for test AMX MOD X in addons\metamod\plugins.ini file by adding the semicolon at the beginning of the line calling amxmodx_mm.dll. Then create a game and try to add a bot. I want to know if it keep crashing/freezing also without AMX X. If this test will pass for You OK - then You can grab the
All-In-One from the filebase. Then rename Your addons directory to addons_old and unzip everything from All-In-One zip file into Your ...\cstrike folder and without changing any settings in any config file try to start the game with default settings All-In-One comes with (and try also add a bot). Then let me know what's happened.